• Program Information

Title  

Dendritic polymers as biocompatible oil spill dispersants

     
Session Title   Technological, Environmental and Policy Developments for Improved Research and Operations in the Gulf of Mexico
     
Presenter Last Name   Ladner
     
Presenter First Name   David
     
Presenter Affiliation   Clemson University
     
Presenter Email   ladner@clemson.edu
     
Authors   David A. Ladner, Clemson University; Nicholas K. Geitner, Clemson University; Muriel M. Steele, Clemson University; Peng Xie, Clemson University; Priyanka Bhattacharya, Pacific Northwestern National Labs; Ran Chen, Clemson University; Andrew Whelton, University of South Alabama; Sean Powers, University of South Alabama; Pu-Chun Ke, Clemson University
     
Abstract   Dendritic polymers have recently been shown to encapsulate polycyclic aromatic hydrocarbons (PAHs) and other hydrophobic materials. We thus hypothesize that crude oil can be dispersed using these materials. Our objective is to gain a fundamental understanding of the interactions of dendritic polymers with crude oil, taking toxicity and biodegradability into consideration. First-phase laboratory results show that poly(amidoamine) dendrimers and hyperbranched poly(ethyleneimine) polymers form complexes with linear (hexadecane) and polyaromatic (phenanthrene) hydrocarbons, increasing the dispersion of these model crude oil components. Ongoing efforts are examining the effects of hydrocarbon-polymer complexes on algal species to determine their biocompatibility. Dendritic polymers will be compared with Corexit 9500A and other conventional dispersants. As a part of this project, community outreach workshops will carry the research knowledge to the public and allow community groups to participate directly in laboratory studies.
     
Presentation Type   Poster
     
Session Number   017
     
Date Monday, January 21
     
Time   1630-1830
     
Location Mardi Gras Ballroom
     
Student? No
     
Invited Talk? No
     

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